/Department of CHEMISTRY


Students

 

 
Department of Chemistry
Willamette University
900 State Street
Salem, OR 97301
Office Tel: 503-370-6013
Office Fax: 503-375-5425


Research

Andrew Duncan : Synthetic Organic and Organometallic Chemistry; Catalysis ...........Assistant Professor  
  Development of chiral organic catalysts derived from 2-amino sugars: simple compounds for tricky tasks.    
   
 

Ring-closing metathesis reactions of allenes: developing new methods for making synthetically challenging large-ring molecules.

David Goodney: Analytical and Environmental Chemistry.....................................................Associate Dean
  Instrumental methods for environmental analysis. For example, UV-visible spectroscopy for measurement of pH.
  Metal ions in the environment, particularly interactions with living organisms and phytoremediation.
   
  Analysis of antioxidants in wine.
   
Karen Holman: Inorganic, Bioinorganic, and Organometallic Chemistry...................Associate Professor
  Ligand exchange reactions of Ru(II) and Ru(III) anti-cancer drugs using infrared spectroelectrochemistry.
  X-ray spectroscopic determination of electron distribution in Ru-Cl bonds in ruthenium-based anti-cancer drugs and their derivatives.
   
  Kinetics of short-lived intermediates generated by laser flash photolysis of metal nitrosyl and carbonyl complexes (in collaboration with Prof. Williamson).
   
Binding and cleavage studies of metal complexes with tRNA (in collaboration with Prof. Kirk).
   
Tony Hoobler: Organic Chemistry..........................................................................Visiting Assistant Professor
  The effect of steric, through-bond and through-space chlorine-chlorine interactions on the conformational stability of molecules and stereochemical outcomes of reactions.
   
  The factors that influence the formation, structure and fate of the oxaphosphetane intermediate in the Wittig reaction.
   
  The role of chlorine-substituted dienophiles and dienes on the stereochemistry of the Diels-Alder adduct.
   
  The application of Spartan, a molecular mechanical and quantum chemical calculations program, to the theoretical study of reactions under kinetic and thermodynamic control.
   
Sarah Kirk: Bioorganic Chemistry........................................................................................Assistant Professor
  Design and synthesis of novel pharmaceuticals utilizing amino acid-aminoglycoside scaffolds.
Investigation of the binding betewen novel molecules and nucleic acid via fluorescence spectroscopy.
Define essential elements within novel molecules that dictate nucleic acid specificity.
   
Art Payton: Theoretical Physical Chemistry.......................................................................Research Professor
  Transport entropies and enthalpies of ions in solution.
Thermoelectric power: theory and experimental observations.
   
Todd Silverstein: Biochemistry...............................................................................................................Professor
  Toxicity of heavy metal ions and metal reactivity with enzymes.
  Enzyme activity in non-aqueous deep eutectic solvents.
   
  Photochemistry of sunscreens: does UV spectroscopy predict control of photoinduced free radical production?
   
How do lipid membrane surfaces differ from the bulk aqueous phase and from the membrane interior? Measuring pH variations.
Degradation of organic pollutants: using UV light and sonication to degrade PCB's, dioxins, antibiotics, and other pollutants.
Arwyn Smalley : Materials/Inorganic/Physical Chemistry..................................Visiting Assistant Professor
  Analyze crystalline materials using powder X-ray diffraction, and use quantitative analysis to determine the amount of crystalline material present.
   
  Use one (or more) of the principles of Green Chemistry to modify an existing Organic Chemistry laboratory experiment to make it greener.
   
  Design a new physical chemistry laboratory experiment (or modify an existing one) to utilize differential scanning calorimetry (rather than bomb or solution calorimetry) to illustrate the concept of calorimetry in the class.
Chuck Williamson: Physical Chemistry..........................................................Chair and Associate Professor
  Thermodynamics and spectroscopic properties of binary liquid mixtures.
  Time-resolved spectroscopy and fast (nanosecond) kinetics.
   
  Laser Doppler velocimetry.

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